The first title in this area in many years, this title brings together all the areas of interest in organic reactions involving carbocations in one handy volume. It covers new areas such as nuclear decay generation, synthetic applications and NMR observations. Also included is extensive and detailed coverage of theoretical and gas phase data.
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Professor Zvi Rappoport, Department of Organic Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel.
Peter J. Stang is a German American chemist and Distinguished Professor of chemistry at the University of Utah. He has also been the editor of the Journal of the American Chemical Society. He is the author of more than 450 scientific publications and several books.
Dicoordinated carbocations, namely vinyl and aryl cations, are part of what is arguably the most important family of reactive intermediates in organic chemistry, i.e., carbocations. The significance of this field was recently recognised with a Nobel Prize to Professor G. A. Olah. Dicoordinated Carbocations summarises the advances in the field achieved by applying computational techniques, mass and NMR spectrometry, nuclear decay, laser flash photolysis, solvolysis and photochemistry, which have provided new and interesting insights into the nature and chemistry of dicoordinated carbocations over the past twenty years. This new understanding allows the synthetic chemist to use vinyl cations in synthetic transformations and natural product synthesis. This monograph has been written for organic chemists but it is also relevant for theoretical and computational, and synthetic chemists.
Dicoordinated carbocations, namely vinyl and aryl cations, are part of what is arguably the most important family of reactive intermediates in organic chemistry, i.e., carbocations. The significance of this field was recently recognised with a Nobel Prize to Professor G. A. Olah. Dicoordinated Carbocations summarises the advances in the field achieved by applying computational techniques, mass and NMR spectrometry, nuclear decay, laser flash photolysis, solvolysis and photochemistry, which have provided new and interesting insights into the nature and chemistry of dicoordinated carbocations over the past twenty years. This new understanding allows the synthetic chemist to use vinyl cations in synthetic transformations and natural product synthesis. This monograph has been written for organic chemists but it is also relevant for theoretical and computational, and synthetic chemists.
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