Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium - Hardcover

Hardcover

ISBN 10: 0854043667 ISBN 13: 9780854043668

Verlag: Royal Society of Chemistry, 2007

Inhaltsangabe

The Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium provides an overview of recent developments, particularly from the last decade, on the chemistry of the chalcogen group elements (S, Se and Te).

This book gives a comprehensive overview on recent developments over the last decade and is ideal for researchers in the fie'd

The Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium provides an overview of recent developments, particularly from the last decade, on the chemistry of the chalcogen group elements (S, Se and Te).

While up to a few decades ago, chalcogen chemistry was mainly centred on sulphur, in recent years the research based on Se and Te has increased dramatically, and has created huge scope for the use of compounds based on this type of chemistry.

This book is organised into two parts, the first of which deals systematically with the chemistry of chalcogens in relation to other group elements in the periodic table.  It also includes an overview of metal-chalcogenides and metal-polychalcogenides.  The second part reflects the interdisciplinary nature of chalcogen chemistry and focuses on biological, materials and supramolecular aspects of the field. 

This book gives a comprehensive overview on recent developments over the last decade and is ideal for researchers in the field.

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The Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium provides an overview of recent developments, particularly from the last decade, on the chemistry of the chalcogen group elements (S, Se and Te). While up to a few decades ago, chalcogen chemistry was mainly centred on sulphur, in recent years the research based on Se and Te has increased dramatically, and has created huge scope for the use of compounds based on this type of chemistry. The Handbook is organised into two parts, the first of which deals systematically with the chemistry of chalcogens in relation to other group elements in the periodic table. It also includes an overview of metal-chalcogenides and metal-polychalcogenides. The second part reflects the interdisciplinary nature of chalcogen chemistry and focuses on biological, materials and supramolecular aspects of the field. This Handbook gives a comprehensive overview on recent developments over the last decade and is ideal for researchers in the field.

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Handbook of Chalcogen Chemistry

New Perspectives in Sulfur, Selenium and Tellurium

By Francesco A. Devillanova

The Royal Society of Chemistry

Copyright © 2007 The Royal Society of Chemistry
All rights reserved.

ISBN: 978-0-85404-366-8

Contents

Chapter 1 Compounds Containing the Boron–Chalcogen B–E (E=S, Se, Te) Bond Michael A. Beckett, 1, 
Chapter 2.1 Thiolates, Selenolates, and Tellurolates M. Concepción Gimeno, 33, 
Chapter 2.2 Recent Developments in the Chemistry of Thio-, Seleno- and Telluro-ethers William Levason and Gillian Reid, 81, 
Chapter 2.3 Chalcogenone C=E compounds Norbert Kuhn and Gaetano Verani, 107, 
Chapter 2.4 Thioamides, Thioureas and Related Selenium and Tellurium Compounds Mamoru Koketsu and Hideharu Ishihara, 145, 
Chapter 3 The Compounds Between Si, Ge and Sn and Chalcogens (S, Se, and Te) Having Both a Single Bond and a Double Bond (Heavy Ketones) Nobuhiro Takeda, Norihiro Tokitoh and Renji Okazaki, 195, 
Chapter 4 Chalcogen–Nitrogen Chemistry Tristram Chivers and Risto S. Laitinen, 223, 
Chapter 5 Chalcogen–Phosphorus (and Heavier Congeners) Chemistry Rob Davies, 286, 
Chapter 6 Chalcogen–Oxygen Chemistry Mathias S. Wickleder, 344, 
COMPOUNDS CONTAINING THE CHALCOGEN–CHALCOGEN E–E BOND (E=S, SE, TE), 
Chapter 7.1 Structure and Bonding of the Neutral Chalcogens and their Polyatomic Cations Ingo Krossing, 381, 
Chapter 7.2 Organochalcogen Multication Species Valentine G. Nenajdenko, Nikolay E. Shevchenko, Elizabeth S. Balenkova and Igor V. Alabugin, 417, 
HALOGEN–CHALCOGEN X–E (X=F, Cl, Br, I; E=S, Se,Te) CHEMISTRY, 
Chapter 8.1 Recent Developments in Binary Halogen–Chalcogen Compounds, Polyanions and Polycations Zhengtao Xu, 457, 
Chapter 8.2 Charge-Transfer (C.-T.) Adducts and Related Compounds Vito Lippolis and Francesco Isaia, 477, 
METAL CHALCOGENIDES, 
Chapter 9.1 Metal Chalcogenides: Clusters, Layers, Nanotubes Maxim N. Sokolov, 503, 
Chapter 9.2 Polychalcogenides William S. Sheldrick, 543, 
MISCELLANEOUS ASPECTS, 
Chapter 10.1 Synthesis and Stereochemistry of Optically Active Chalcogen Compounds Toshio Shimizu and Nobumasa Kamigata, 577, 
Chapter 10.2 1,1-Dithiolato Ligands and Related Selenium and Tellurium Compounds Ionel Haiduc, 593, 
Chapter 10.3 Hypervalent Chalcogen Compounds Waro Nakanishi, 644, 
BIOLOGICAL CHEMISTRY, 
Chapter 11.1 Chalcogens (S, Se, Te) in Microorganisms and Plants Thomas G. Chasteen and Ronald Bentley, 671, 
Chapter 11.2 Metal-Sulfur Clusters as the Model for the Active Sites of Metalloenzymes Yasushi Mizobe, 714, 
MATERIAL CHEMISTRY, 
Chapter 12.1 Stable Chalcogen Radicals Jeremy M. Rawson and Antonio Alberola, 733, 
Chapter 12.2 Chalcogen-Rich Compounds as Electron Donors Thomas D. Westgate and Peter J. Skabara, 763, 
Chapter 12.3 1,2-Dithiolene Ligands and Related Selenium and Tellurium Compounds Massimiliano Arca and M. Carla Aragoni, 797, 
SUPRAMOLECULAR CHEMISTRY, 
Chapter 13 Chalcogen-Halogen Secondary Bonds in Self-Assembling of Supramolecular Structures Wolf-Walther du Mont and Cristian George Hrib, 833, 
Subject Index, 873, 

CHAPTER 1

Compounds Containing the Boron–Chalcogen B–E (E=S, Se, Te) Bond

MICHAEL A. BECKETT

School of Chemistry, University of Wales, Bangor, LL57 2UW, UK

1.1 Introduction

This chapter focusses on compounds with chalcogen (E=S, Se, Te) to B bonds and reviews the chemical literature over the period 1990–2004. Although every effort has been made to include all important advances in all sections, the review is not claimed to be comprehensive. The literature has been surveyed principally by independent keyword searches of the primary chemical journals and ISI Web of Science augmented by ACS Chemical Abstracts and RSC Annual Reports on the Progress of chemistry, Section A (Inorganic Chemistry). The review is structured so that relevant books, conference proceedings, and review articles that have appeared over the period are described first, and then the chemistry of specific topics are explored in more detail. Polyhedral boron hydride cluster species forms a major section of this review and this section is conveniently divided into sub-sections depending upon the nature of the B–E linkages. The remaining principal sections of this review cover two other important themes: heterocycles containing B–E linkages, and thioborate and selenoborate chemistry. The review concludes with a miscellaneous section, which includes B–E reagents.

1.2 Books and Review Articles

Sections relating to compounds with B–E bonds can be found in the authoritative review chapters found in Comprehensive Organometallic Chemistry II (vol 1); these chapters generally survey the literature over the period 1982-1994. In particular, Chapter 4 has a section reporting on cyclic systems with B–E (E=S, Se) bonds, and Chapter 7 surveys main group heteroboranes, with a section on thiaboranes and their metal complexes. Metalloboranes, car-boranes, and metallocarboranes are reviewed in Chapters 8, 6, and 9, respectively, with many such clusters containing exo B–E bonds. The 'International Meeting on Boron Chemistry' (IMEBORON) has met on a number of occasions over the review period and the proceedings of these conferences have been published; these collections give an interesting perspective on the development of boron chemistry in general but with many relevant articles. A review on chalcogenoboron hydrides was published in 1997 giving a historical viewpoint and covering the literature to 1997. An overview of heteroboranes in which p-block elements (including S, Se, and Te) have replaced one or more vertices in parent borane cages was reported in 2002. The topic of thioborate and selenoborates have been reviewed on a number of occasions, with the most recent in 2003 discussing their diverse structures, which range from rings, through clusters to 3d networks.

1.3 Polyhedral Boron Hydride Derivatives

1.3.1 Species with Exo B–Chalcogen Bonds

1.3.1.1 Boranes and Heteroboranes

There were a considerable number of reports over the period 1990–2004 on polyhedral boron hydride species with exo–chalcogen bonds and the following section is structured in terms of increasing polyhedral size. There were also a few reports on polyhedral carborane species, which are at the end of this section, but there were no reports on other heteroborane species with exo- chalcogen bonds.

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Details zur Ausgabe

• Verlag: Royal Society of Chemistry
• Erscheinungsdatum: 2007
• Sprache: Englisch
• ISBN 10: 0854043667
• ISBN 13: 9780854043668
• Einband: Gebundene Ausgabe
• Auflage: 1
• Anzahl der Seiten: 884
• Herausgeber: Devillanova Francesco A.
• Kontakt zum Hersteller: Nicht verfügbar
• Verantwortliche Person: Nicht verfügbar