The Science of Chocolate (RSC Paperbacks) - Softcover

Beckett, S. T.

 
9780854046003: The Science of Chocolate (RSC Paperbacks)

Inhaltsangabe

"Chocolate is available to today's consumers in a variety of colours, shapes and textures. But how many of us, as we savour our favourite brand, consider the science that has gone into its manufacture? This book describes the complete chocolate making process, from the growing of the beans to the sale in the shops. The Science of Chocolate first describes the history of this intriguing substance. Subsequent chapters cover the ingredients and processing techniques, enabling the reader to discover not only how confectionery is made but also how basic science plays a vital role with coverage of scientific principles such as latent and specific heat, Maillard reactions and enzyme processes. There is also discussion of the monitoring and controlling of the production process, and the importance, and variety, of the packaging used today. A series of experiments, which can be adapted to suit students of almost any age, is included to demonstrate the physical, chemical or mathematical principles involved. Ideal for those studying food science or about to join the confectionery industry, this mouth-watering title will also be of interest to anyone with a desire to know more about the production of the world's favourite confectionery."

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The Science of Chocolate

By Stephen T. Beckett

The Royal Society of Chemistry

Copyright © 2000 The Royal Society of Chemistry
All rights reserved.
ISBN: 978-0-85404-600-3

Contents

Glossary, xii,
Chapter 1 The History of Chocolate, 1,
Chapter 2 Chocolate Ingredients, 8,
Chapter 3 Cocoa Bean Processing, 31,
Chapter 4 Liquid Chocolate Making, 49,
Chapter 5 Controlling the Flow Properties of Liquid Chocolate, 66,
Chapter 6 Crystallising the Fat in Chocolate, 85,
Chapter 7 Manufacturing Chocolate Products, 104,
Chapter 8 Analytical Techniques, 127,
Chapter 9 Chocolate Products and Packaging, 143,
Chapter 10 Experiments with Chocolate and Chocolate Products, 152,
Subject Index, 170,


CHAPTER 1

The History of Chocolate


Chocolate is almost unique as a food in that it is solid at normal room temperatures yet melts easily within the mouth. This is because the fat in it, which is called cocoa butter, is mainly solid at temperatures below 25 °C when it holds all the solid sugar and cocoa particles together. The fat is, however, almost entirely liquid at body temperature, enabling the particles to flow past one another, so the chocolate becomes a smooth liquid when it is heated in the mouth. Chocolate also has a sweet taste that is attractive to most people.

Strangely chocolate began as a rather astringent, fatty and unpleasant tasting drink and the fact that it was developed at all is one of the mysteries of history.


CHOCOLATE AS A DRINK

The first known cocoa plantations were established by the Maya in the lowlands of south Yucatan about 600 ad. Cocoa trees were being grown by the Aztecs of Mexico and the Incas of Peru when the Europeans discovered central America . The beans were highly prized and used as money as well as to produce a drink known as chocolatl. The beans were roasted in earthenware pots and crushed between stones, sometimes using decorated heated tables and mill stones, similar to the one illustrated in Figure 1.1. They could then be kneaded into cakes, which could be mixed with cold water to make a drink. Vanilla, spices or honey were often added and the drink whipped to make it frothy. The Aztec Emperor Montezeuma was said to have drunk 50 jars of this beverage per day.

Christopher Columbus bought back some cocoa beans to Europe as a curiosity, but it was only after the Spaniards conquered Mexico that Don Cortez introduced the drink to Spain in the 1520s. Here sugar was added to overcome some of the bitter, astringent flavours, but the drink remained virtually unknown in the rest of Europe for almost a hundred years, coming to Italy in 1606 and France in 1657. It was very expensive and, being a drink for the aristocracy, its spread was often connected to connections between powerful families. For example the Spanish princess, Anna of Austria, introduced it to her husband King Louis XIII of France and the French court in about 1615. Here Cardinal Richelieu enjoyed it both as a drink and to aid his digestion. Its flavour was not liked by everyone and one Pope in fact declared that it could be drunk during a fast, because its taste was so bad.

The first chocolate drinking houses were established in London in 1657 and it was mentioned in Pepys's Diary of 1664 where he wrote that 'jocolatte' was 'very good'. In 1727 milk was being added to the drink. This invention is generally attributed to Nicholas Sanders. During the 18th century White's Chocolate House became the fashionable place for young Londoners, while politicians of the day went to the Cocoa Tree Chocolate House. These were much less rowdy than the taverns of the period. It remained however, very much a drink for the wealthy.

One problem with the chocolate drink was that it was very fatty. Over half of the cocoa bean is made up of cocoa butter. This will melt in hot water making the cocoa particles hard to disperse as well as looking unpleasant because of fat coming to the surface. The Dutch, however, found a way of improving the drink by removing part of this fat. In 1828 Van Houten developed the cocoa press. This was quite remarkable, as his entire factory was manually operated at the time. The cocoa bean cotyledons (known as cocoa nibs) were pressed to produce a hard 'cake' with about half the fat removed. This was milled into a powder, which could be used to produce a much less fatty drink. In order to make this powder disperse better in the hot water or milk, the Dutch treated the cocoa beans during the roasting process with an alkali liquid. This has subsequently become known as the Dutching process. By changing the type of alkalising agent, it also became possible to adjust the colour of the cocoa powder.


EATING CHOCOLATE

Having used the presses to remove some of the cocoa butter, the cocoa powder producers were left trying to find a market for this fat. This was solved by confectioners finding that eating chocolate could be produced by adding it to a milled mixture of sugar and cocoa nibs. (The ingredients used to make dark chocolate are shown in Figure 1.2.) If only the sugar and cocoa nibs were milled and mixed together they would produce a hard crumbly material. Adding the extra fat enabled all the solid particles to be coated with fat and thus form the hard uniform bar that we know today, which will melt smoothly in the mouth.

Almost twenty years after the invention of the press, in 1847, the first British factory to produce a plain eating chocolate was established in Bristol in the UK by Joseph Fry.

Unlike Van Houten, Fry used the recently developed steam engines to power his factory. It is interesting to note that many of the early chocolate companies, including Cadbury, Rowntree and Hershey (in the USA) were founded by Quakers or people of similar religious beliefs. This may have been because their pacifist and teetotal beliefs prevented them working in many industries. The chocolate industry was, however, regarded as being beneficial to people. Both Cadbury and Rowntree moved to the outside of their cities at the end of the 1890s, where they built 'garden' villages for some of their workers. Fry remained in the middle of Bristol and did not expand as quickly as the other two companies. It eventually became part of Cadbury.

With the development of eating chocolate the demand for cocoa greatly increased. Initially much of the cocoa came from the Americas. The first cocoa plantation in Bahia in Brazil was established in 1746. Even before this, the Spaniards had taken cocoa trees to Fernando Po (Biyogo), of the coast of Africa, and this soon became an important growing area. In 1879 a West African blacksmith took some plants home to the Gold Coast (now Ghana). The British Governor realised its potential and encouraged the planting of trees, with the result that Ghana has become a major source of quality cocoa. Other European powers also encouraged the growing of cocoa in their tropical colonies, e.g. France in the Ivory Coast (Côte D'voire), which is now the world's largest producer of cocoa.

The chocolate made by Fry was initially a plain block and it was only in 1876 that the first milk chocolate was made by Daniel Peter in Switzerland. Chocolate can not contain much moisture, because water reacts with the sugar and turns melted chocolate into a paste rather than a smoothly flowing liquid (see Project 5 in Chapter 10). As little as 2% of moisture can give a product a poor shelf-life as well as an inferior texture. This meant that Daniel Peter had to find some way of drying the plentiful...

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