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Bioinspired Mono- and Dinuclear Nickel, Zinc and Copper Complexes for the Binding and Transformation of Biorelevant Substrates
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- VerlagCuvillier Verlag
- Erscheinungsdatum2016
- ISBN 10 3736992513
- ISBN 13 9783736992511
- EinbandRústica
- Anzahl der Seiten252
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Bioinspired Mono- and Dinuclear Nickel, Zinc and Copper Complexes for the Binding and Transformation of Biorelevant Substrates
Verlag:
Cuvillier Mai 2016
(2016)
ISBN 10: 3736992513
ISBN 13: 9783736992511
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Buchbeschreibung Taschenbuch. Zustand: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -The synthesis of model systems is of great interest for understanding metalloenzyme active site features, and for developing biomimetic catalysts. Compartmental ligands based on macrocyclic systems and on 3,5-disubstituted pyrazolate bridges are well suited. Especially the latter ones were generated to synthesis highly preorganised bimetallic complexes with tuneable metal¿¿¿metal separations in the range 3.5¿4.5 Å. Appending second sphere functions for H-bonding interactions may enhance, in a biomimetic approach, the activation of bound substrates or the stabilisation of catalytic intermediates. With these ligands, synthetic and functional model complexes based on the proteins urease, phosphotriesterase and hemocyanin should be synthesised and characterised on their binding properties and their abilities to transform biorelevant substrates like urea, phosphoesters and dioxygen. For their characterisation and catalytical properties several analytical methods like UV/vis, IR, NMR and resonance Raman spectroscopy as well as mass spectrometry were used. 252 pp. Englisch. Bestandsnummer des Verkäufers 9783736992511
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Bioinspired Mono- and Dinuclear Nickel, Zinc and Copper Complexes for the Binding and Transformation of Biorelevant Substrates
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Buchbeschreibung Taschenbuch. Zustand: Neu. nach der Bestellung gedruckt Neuware - Printed after ordering - The synthesis of model systems is of great interest for understanding metalloenzyme active site features, and for developing biomimetic catalysts. Compartmental ligands based on macrocyclic systems and on 3,5-disubstituted pyrazolate bridges are well suited. Especially the latter ones were generated to synthesis highly preorganised bimetallic complexes with tuneable metal¿¿¿metal separations in the range 3.5¿4.5 Å. Appending second sphere functions for H-bonding interactions may enhance, in a biomimetic approach, the activation of bound substrates or the stabilisation of catalytic intermediates. With these ligands, synthetic and functional model complexes based on the proteins urease, phosphotriesterase and hemocyanin should be synthesised and characterised on their binding properties and their abilities to transform biorelevant substrates like urea, phosphoesters and dioxygen. For their characterisation and catalytical properties several analytical methods like UV/vis, IR, NMR and resonance Raman spectroscopy as well as mass spectrometry were used. Bestandsnummer des Verkäufers 9783736992511
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Bioinspired Mono- and Dinuclear Nickel, Zinc and Copper Complexes for the Binding and Transformation of Biorelevant Substrates
Verlag:
Jentzsch-Cuvillier, Annette
(2016)
ISBN 10: 3736992513
ISBN 13: 9783736992511
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Buchbeschreibung Zustand: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. KlappentextrnrnThe synthesis of model systems is of great interest for understanding metalloenzyme active site features, and for developing biomimetic catalysts. Compartmental ligands based on macrocyclic systems and on 3,5-disubstituted pyrazol. Bestandsnummer des Verkäufers 121798383
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