A general dynamic model for continuous EPDM polymerization in which crosslinking and gel formation are attributable to reactions between pendant double bonds has been developed. A pseudo- kinetic rate constant method is introduced to construct a moment model for a pseudo-homopolymer that approximates the behavior of the actual terpolymer under long chain and quasi-steady state assumptions. The proposed dynamic model is capable of predicting polydispersities and molecular weight distributions near the gel point. A parameter selection procedure is proposed to determine the kinetic parameters that can be estimated from the limited plant data. The procedure is based on the steady-state parameter output sensitivity matrix. The overall effect of each parameter on the measured outputs is determined using Principal Component Analysis (PCA). The key kinetic parameters determined by the parameter selection procedure were estimated from steady-state data extracted from dynamic plant data, using a newly developed steady state detection tool.
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Rujun Li received his BS and MS, both in chemical engineering from Tianjin University in China and PhD, also in chemical engineering from Louisiana State University in the United States. He is now working in Houston, TX, US on developing operator training simulators (OTS) for chemicals and refineries.
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Taschenbuch. Zustand: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -A general dynamic model for continuous EPDM polymerization in which crosslinking and gel formation are attributable to reactions between pendant double bonds has been developed. A pseudo- kinetic rate constant method is introduced to construct a moment model for a pseudo-homopolymer that approximates the behavior of the actual terpolymer under long chain and quasi-steady state assumptions. The proposed dynamic model is capable of predicting polydispersities and molecular weight distributions near the gel point. A parameter selection procedure is proposed to determine the kinetic parameters that can be estimated from the limited plant data. The procedure is based on the steady-state parameter output sensitivity matrix. The overall effect of each parameter on the measured outputs is determined using Principal Component Analysis (PCA). The key kinetic parameters determined by the parameter selection procedure were estimated from steady-state data extracted from dynamic plant data, using a newly developed steady state detection tool. 224 pp. Englisch. Bestandsnummer des Verkäufers 9783838313733
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Zustand: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. Autor/Autorin: Li RujunRujun Li received his BS and MS, both in chemical engineering from Tianjin University in China and PhD, also in chemical engineering from Louisiana State University in the United States. He is now working in Houston, TX, . Bestandsnummer des Verkäufers 5412066
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Taschenbuch. Zustand: Neu. DYNAMIC MODELING AND PARAMETER ESTIMATION FOR AN EPDM PROCESS | Rujun Li | Taschenbuch | 224 S. | Englisch | 2010 | LAP LAMBERT Academic Publishing | EAN 9783838313733 | Verantwortliche Person für die EU: BoD - Books on Demand, In de Tarpen 42, 22848 Norderstedt, info[at]bod[dot]de | Anbieter: preigu. Bestandsnummer des Verkäufers 101462512
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Taschenbuch. Zustand: Neu. This item is printed on demand - Print on Demand Titel. Neuware -A general dynamic model for continuous EPDM polymerization in which crosslinking and gel formation are attributable to reactions between pendant double bonds has been developed. A pseudo- kinetic rate constant method is introduced to construct a moment model for a pseudo-homopolymer that approximates the behavior of the actual terpolymer under long chain and quasi-steady state assumptions. The proposed dynamic model is capable of predicting polydispersities and molecular weight distributions near the gel point. A parameter selection procedure is proposed to determine the kinetic parameters that can be estimated from the limited plant data. The procedure is based on the steady-state parameter output sensitivity matrix. The overall effect of each parameter on the measured outputs is determined using Principal Component Analysis (PCA). The key kinetic parameters determined by the parameter selection procedure were estimated from steady-state data extracted from dynamic plant data, using a newly developed steady state detection tool.VDM Verlag, Dudweiler Landstraße 99, 66123 Saarbrücken 224 pp. Englisch. Bestandsnummer des Verkäufers 9783838313733
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Taschenbuch. Zustand: Neu. nach der Bestellung gedruckt Neuware - Printed after ordering - A general dynamic model for continuous EPDM polymerization in which crosslinking and gel formation are attributable to reactions between pendant double bonds has been developed. A pseudo- kinetic rate constant method is introduced to construct a moment model for a pseudo-homopolymer that approximates the behavior of the actual terpolymer under long chain and quasi-steady state assumptions. The proposed dynamic model is capable of predicting polydispersities and molecular weight distributions near the gel point. A parameter selection procedure is proposed to determine the kinetic parameters that can be estimated from the limited plant data. The procedure is based on the steady-state parameter output sensitivity matrix. The overall effect of each parameter on the measured outputs is determined using Principal Component Analysis (PCA). The key kinetic parameters determined by the parameter selection procedure were estimated from steady-state data extracted from dynamic plant data, using a newly developed steady state detection tool. Bestandsnummer des Verkäufers 9783838313733
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