Ionic liquids, use and specific task as solvent in catalytic reaction - Softcover

GUTEL, Thibaut

Softcover

ISBN 10: 383833406X ISBN 13: 9783838334066

Verlag: LAP Lambert Academic Publishing, 2010

Inhaltsangabe

Ionic liquids, associations of organic cations and anions, are media organized over several nanometers and present a segregation in polar and nonpolar microdomains. As they are used as solvents for catalytic reactions, they can induce specific solvation phenomena. For instance, ion exchange reactions in some catalytic systems and some py-cation interactions with unsaturated hydrocarbons have been observed by NMR. The consequences of the specific solvation on hydrogenation reactions have been studied. It appears that the stronger the interactions between IL and reactants are, the slower the reactions are. The presence of nonpolar and polar microdomains leads to a preferential solvation of organometallic complexes in apolar pockets that enable the use of these media as supramolecular matrices and to control the crystal growth of metal nanoparticles generated in situ according to the alkyl chain length and the temperature.

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Über die Autorin bzw. den Autor

After a Master in chemistry and chemical engineering at ESCOM (Ecole Supérieure de Chimie Organique et Minérale, Cergy-Pontoise, France), Thibaut GUTEL has completed his PhD in chemistry under the supervision of Dr C. Santini and Dr Y. Chauvin in the "Laboratoire de Chimie Organométallique de Surface" directed by Dr J.M. Basset in 2007.

Details zur Ausgabe

• Verlag: LAP Lambert Academic Publishing
• Erscheinungsdatum: 2010
• Sprache: Englisch
• ISBN 10: 383833406X
• ISBN 13: 9783838334066
• Einband: Taschenbuch
• Anzahl der Seiten: 144
• Kontakt zum Hersteller: Nicht verfügbar
• Verantwortliche Person: KreGa Onlinehandel GmbH; 4950000000000; info@krega-onlinehandel.de; ; Birkenweg 31; Brakel; 33034; Deutschland