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Thermodynamics Behavior for Polymer Blends: Prediction of the behavior for polymer blends using thermodynamic model - Softcover

Farhod, Khalid

 
9786138934639: Thermodynamics Behavior for Polymer Blends: Prediction of the behavior for polymer blends using thermodynamic model

Inhaltsangabe

The aim of the present work was to study the thermodynamic behavior of polymer blend via determination of miscibility . Miscibility (or immiscibility) tests are performed in three techniques: viscometry method, DSC analyzer and FTIR to test polymer blend in solid state. Two polymer blends were prepared . the first one was Poly methyl methacrylate (PMMA) and Poly vinyl acetate (PVAc) , and the second was Poly vinyl chloride (PVC) and Polystyrene (PS).Calculations of Flory -Huggins interaction parameter for two systems was performed and the results pointed to miscible blend for PMMA/PVAc blends and immiscible blend for PVC/PS blends. So there is a good agreement between the experimental results and calculations of interaction parameter based on Flory - Huggins theory .Differential scanning colarimetry (DSC) analyzer gave thermogram curves revealing one glass transition temperature for PMMA/PVAc blends except at (20/80) composition , this indicates that the system is miscible except at (20/80) composition . But , PVC/PS blends showed two glass transition temperature so the system is immiscible.FTIR analysis for PMMA/PVAc blends depicted a weak interaction between the two polymers

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Über die Autorin bzw. den Autor

Dr. Khalid Farhod has obtained his Ph.D. degree in Chemical Engineering in 2002. Since then he has worked in different projects in the field of Thermodynamics, Vapor - Liquid Equilibrium, Liquid - Liquid Equilibrium and  Ionic Liquids Membrane Separation . He now works the Petroleum & Gas Engineering Department,University of Thi Qar, Iraq.

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