Synthesis of Lanthanide and Actinide Compounds: 2 (Topics in F-Element Chemistry) - Softcover

 
9789401056724: Synthesis of Lanthanide and Actinide Compounds: 2 (Topics in F-Element Chemistry)
Softcover
ISBN 10: 9401056722 ISBN 13: 9789401056724
Verlag: Springer, 2012

Inhaltsangabe

The history of the rare earths has entered its third century; trans uranium elements are now a half century old. Both the lanthanide and actinide ele­ ments, 30 elements altogether, are f elements, meaninj that their metallic 2 1 1 electronic configurations are typically 6s 5d 4f" and 7s 6d 5f" respectively. To an elementary approximation as summarized in the ’average inorganic chemistry textbook, these configurations cause their chemistry to be described by the trivalent state accompanied by less interesting effects such as the lanthanide contraction. However, the discovery of divalent and tetravalent lanthanides and di- to seven-valent actinides hinted at the existence of more interesting although still classic solid-state and coor­ dination chemistry. Metallic halides and chalcogenides and electron-poor cluster compounds have been the outgrowth of many synthetic efforts during the past 25 years or so. These days, one can say that the lan­ thanides and actinides are not at all boring; the fascination arises from every element being an individual, having its own chemistry.

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Reseña del editor

The history of the rare earths has entered its third century; trans uranium elements are now a half century old. Both the lanthanide and actinide ele­ ments, 30 elements altogether, are f elements, meaninj that their metallic 2 1 1 electronic configurations are typically 6s 5d 4f" and 7s 6d 5f" respectively. To an elementary approximation as summarized in the 'average inorganic chemistry textbook, these configurations cause their chemistry to be described by the trivalent state accompanied by less interesting effects such as the lanthanide contraction. However, the discovery of divalent and tetravalent lanthanides and di- to seven-valent actinides hinted at the existence of more interesting although still classic solid-state and coor­ dination chemistry. Metallic halides and chalcogenides and electron-poor cluster compounds have been the outgrowth of many synthetic efforts during the past 25 years or so. These days, one can say that the lan­ thanides and actinides are not at all boring; the fascination arises from every element being an individual, having its own chemistry.

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Verlag
Springer
Erscheinungsdatum
2012
Sprache
Englisch
ISBN 10 
9401056722
ISBN 13 
9789401056724
Einband
Tapa blanda
Anzahl der Seiten
388
Herausgeber
Meyer G., Morss L.R.
Kontakt zum Hersteller
Nicht verfügbar
Verantwortliche Person
CMN Printpool Inh. Mathis Neumann
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Hamburg
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Weitere beliebte Ausgaben desselben Titels

9780792310181: Synthesis of Lanthanide and Actinide Compounds: 2 (Topics in F-Element Chemistry)

Vorgestellte Ausgabe

ISBN 10:  0792310187 ISBN 13:  9780792310181
Verlag: Springer, 1990
Hardcover