Reduction Kinetics of Iron Ore-Graphite Composite Pellets

Golap Mohammad Chowdhury

ISBN 10: 384335782X / ISBN 13: 9783843357821

Verlag: LAP LAMBERT Academic Publishing Nov 2010, 2010

Beschreibung

This item is printed on demand - it takes 3-4 days longer - Neuware -The rate of reduction of iron ore-graphite composite pellets under inert and reducing atmospheres has been investigated in a tailor made thermo-gravimetric packed-bed reactor. A very low overall apparent activation energy estimated from experimental data indicates that the reduction is not chemical kinetics controlled. A kinetic model has been developed to quantify the temporal evolution of different iron oxide phases and metallic iron. The rate-dependent parameters (frequency factors and activation energy) have been estimated from experimental data by applying an optimization tool (Genetic Algorithm). The predicted phases at various degrees of reduction were verified by X-ray diffraction and metallographic investigation. A simplified thermal model has also been developed to show the role of heat transfer on the kinetics of the reduction process under inert atmosphere. The reduction kinetics of the composite pellets in the packed bed under reactive atmosphere is not heat transfer controlled and might possibly be controlled by CO-gas mass transfer through the pellets. 112 pp. Englisch. Bestandsnummer des Verkäufers 9783843357821

Bibliografische Details

Titel: Reduction Kinetics of Iron Ore-Graphite ...

Verlag: LAP LAMBERT Academic Publishing Nov 2010

Erscheinungsdatum: 2010

Einband: Taschenbuch

Zustand: Neu

Über diesen Titel

Inhaltsangabe:

The rate of reduction of iron ore-graphite composite pellets under inert and reducing atmospheres has been investigated in a tailor made thermo-gravimetric packed-bed reactor. A very low overall apparent activation energy estimated from experimental data indicates that the reduction is not chemical kinetics controlled. A kinetic model has been developed to quantify the temporal evolution of different iron oxide phases and metallic iron. The rate-dependent parameters (frequency factors and activation energy) have been estimated from experimental data by applying an optimization tool (Genetic Algorithm). The predicted phases at various degrees of reduction were verified by X-ray diffraction and metallographic investigation. A simplified thermal model has also been developed to show the role of heat transfer on the kinetics of the reduction process under inert atmosphere. The reduction kinetics of the composite pellets in the packed bed under reactive atmosphere is not heat transfer controlled and might possibly be controlled by CO-gas mass transfer through the pellets.

Über die Autorinnen und Autoren:

Dr. Golap Mohammad Chowdhury; Deputy Manager, Iron & Sinter, Research & Develpoment Centre for Iron & Steel,SAIL,Ranchi,India. Dr. Gour Gopal Roy; Professor, Dept. of Metallurical & Materials Engg., IIT, Kharagpur, India. Dr. Sanat Kumar Roy; Professor & HoD, Dept. of Metallurical & Materials Engg., IIT, Kharagpur, India.

Dr. Golap Mohammad Chowdhury; Deputy Manager, Iron & Sinter, Research & Develpoment Centre for Iron & Steel,SAIL,Ranchi,India. Dr. Gour Gopal Roy; Professor, Dept. of Metallurical & Materials Engg., IIT, Kharagpur, India. Dr. Sanat Kumar Roy; Professor & HoD, Dept. of Metallurical & Materials Engg., IIT, Kharagpur, India.

Dr. Golap Mohammad Chowdhury; Deputy Manager, Iron & Sinter, Research & Develpoment Centre for Iron & Steel,SAIL,Ranchi,India. Dr. Gour Gopal Roy; Professor, Dept. of Metallurical & Materials Engg., IIT, Kharagpur, India. Dr. Sanat Kumar Roy; Professor & HoD, Dept. of Metallurical & Materials Engg., IIT, Kharagpur, India.