9783540875666 - three-dimensional free-radical polymerization: cross-linked and hyper-branched polymers von korolyov, gennady v.; mogilevich, michael (13 Ergebnisse)
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Gebundene Ausgabe. Zustand: Wie neu. 288 Seiten; neuwertig und ungelesen ZA 9322276 Sprache: Englisch Gewicht in Gramm: 600.
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Zustand: Sehr gut. Zustand: Sehr gut | Seiten: 288 | Sprache: Englisch | Produktart: Bücher | At present, three-dimensional free-radical polymerization (TFRP) is a special ?eld of radical polymerization. TFRP is characterized by speci?c kinetic regularities and mechanisms of processes for the formation of cross-linked or hyper-b…ranched po- mers, and they are different from the kinetics and mechanism of classical radical polymerization. The fundamental studies of kinetics and mechanism of TFRP with formation of cross-linked polymers have been carried out in three stages. The ?rst stage lasted from 1960 until 1983, and the main mechanisms of TFRP of oligo(acrylates) were established during this stage [1¿3]. Condensation telomerization, being a universal oligo(acrylate) synthesis procedure, allows us to vary certain molecular parameters, such as length and ?exibility of oligomeric blocks, number and type of reactive groups (methacrylic or acrylic groups), and chemical nature of atomic groups of an oligomeric block, which represent the centers of strong intermolecular interactions. For this reason, oligo(acrylates) were very convenient compounds for establi- ing the main kinetic regularities of TFRP and regularities of formation of polymer three-dimensional cross-linkedstructures,according totheso-calledmicrohetero- neous mechanism (G.V. Korolev, 1977), at the topological and morphological levels.
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Sprache: Englisch
Verlag: Springer Berlin Heidelberg, Springer Berlin Heidelberg, 2009
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Buch. Zustand: Neu. Druck auf Anfrage Neuware - Printed after ordering - At present, three-dimensional free-radical polymerization (TFRP) is a special eld of radical polymerization. TFRP is characterized by speci c kinetic regularities and mechanisms of processes for the formation of cross-linked or hyper-branched po- mers, and…they are different from the kinetics and mechanism of classical radical polymerization. The fundamental studies of kinetics and mechanism of TFRP with formation of cross-linked polymers have been carried out in three stages. The rst stage lasted from 1960 until 1983, and the main mechanisms of TFRP of oligo(acrylates) were established during this stage [1 3]. Condensation telomerization, being a universal oligo(acrylate) synthesis procedure, allows us to vary certain molecular parameters, such as length and exibility of oligomeric blocks, number and type of reactive groups (methacrylic or acrylic groups), and chemical nature of atomic groups of an oligomeric block, which represent the centers of strong intermolecular interactions. For this reason, oligo(acrylates) were very convenient compounds for establi- ing the main kinetic regularities of TFRP and regularities of formation of polymer three-dimensional cross-linkedstructures,according totheso-calledmicrohetero- neous mechanism (G.V. Korolev, 1977), at the topological and morphological levels.
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Hardcover. Zustand: Brand New. 1st edition. 270 pages. 9.50x6.50x0.75 inches. In Stock.
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Buch. Zustand: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -At present, three-dimensional free-radical polymerization (TFRP) is a special eld of radical polymerization. TFRP is characterized by speci c kinetic regularities and mechanisms of processes for the formation of cross-linked or hyper-branche…d po- mers, and they are different from the kinetics and mechanism of classical radical polymerization. The fundamental studies of kinetics and mechanism of TFRP with formation of cross-linked polymers have been carried out in three stages. The rst stage lasted from 1960 until 1983, and the main mechanisms of TFRP of oligo(acrylates) were established during this stage [1 3]. Condensation telomerization, being a universal oligo(acrylate) synthesis procedure, allows us to vary certain molecular parameters, such as length and exibility of oligomeric blocks, number and type of reactive groups (methacrylic or acrylic groups), and chemical nature of atomic groups of an oligomeric block, which represent the centers of strong intermolecular interactions. For this reason, oligo(acrylates) were very convenient compounds for establi- ing the main kinetic regularities of TFRP and regularities of formation of polymer three-dimensional cross-linkedstructures,according totheso-calledmicrohetero- neous mechanism (G.V. Korolev, 1977), at the topological and morphological levels. 288 pp. Englisch.
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Zustand: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. First book on the subject comprising the research results of the last 40 yearsIncludes synthesis, mechanism and physico-mechanical properties, thus important for the specialist in new hightech areasThree-Dimensional Fre…e-Radical Polymeriza.
Sprache: Englisch
Verlag: Springer Berlin Heidelberg, Springer Berlin Heidelberg Jan 2009, 2009
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Buch. Zustand: Neu. This item is printed on demand - Print on Demand Titel. Neuware -At present, three-dimensional free-radical polymerization (TFRP) is a special eld of radical polymerization. TFRP is characterized by speci c kinetic regularities and mechanisms of processes for the formation of cross-linked or hyper-branched po…- mers, and they are different from the kinetics and mechanism of classical radical polymerization. The fundamental studies of kinetics and mechanism of TFRP with formation of cross-linked polymers have been carried out in three stages. The rst stage lasted from 1960 until 1983, and the main mechanisms of TFRP of oligo(acrylates) were established during this stage [1¿3]. Condensation telomerization, being a universal oligo(acrylate) synthesis procedure, allows us to vary certain molecular parameters, such as length and exibility of oligomeric blocks, number and type of reactive groups (methacrylic or acrylic groups), and chemical nature of atomic groups of an oligomeric block, which represent the centers of strong intermolecular interactions. For this reason, oligo(acrylates) were very convenient compounds for establi- ing the main kinetic regularities of TFRP and regularities of formation of polymer three-dimensional cross-linkedstructures,according totheso-calledmicrohetero- neous mechanism (G.V. Korolev, 1977), at the topological and morphological levels.Springer-Verlag GmbH, Tiergartenstr. 17, 69121 Heidelberg 288 pp. Englisch.
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Zustand: New. Print on Demand pp. 288 52:B&W 6.14 x 9.21in or 234 x 156mm (Royal 8vo) Case Laminate on White w/Gloss Lam.
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Zustand: New. PRINT ON DEMAND pp. 288.
