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In den WarenkorbPaperback. Zustand: New. Ever since humans have existed, they have impacted the earth in many different ways (Redman, 1999). Currently, important impacts are associated with the excessive use of non-renewable fossil fuels such as coal, oil and natural gas. Most fossil fuels are used for electricity generation, heating and mobility (eia, 2011), and as feedstock in the chemical industry (IEA et al., 2013). Moreover, the use of fossil fuels is associated with carbon dioxide emissions (CO2) (IEA, 2014; Leimk¨uhler, 2010). Emitting CO2 into the atmosphere leads to global warming and disrupts the natural carbon cycle (Stocker et al., 2013). To close the disrupted carbon cycle, CO2 can be captured and re-utilized, thereby mitigating global warming and saving fossil resources (Styring et al., 2014).CO2 can be captured from current anthropogenic CO2 sources or directly from the atmosphere. Captured CO2 can then be utilized as valuable physical product "as such"or as alternative carbon feedstock for fuels, chemicals and materials. The general concept of CO2 Capture and Utilization (CCU) can be considered established: already today, CO2 is captured and utilized in processes in the chemical industry (Aresta et al., 2014). However, the scope of CO2 utilization is limited. Despite the existing industrial implementations as well as continuous progress and current efforts in CCU research, most CCU technologies are still in early stages of development. Besides the limited technological readiness, CCU is intrinsically challenging since both capture and utilization of CCU typically require substantial amounts of energy (Sakakura et al., 2007). If the provision of energy relies on fossil resources, indirect CO2 emissions are caused. Therefore, the intuitively expected environmental benefits from using CO2 are not given by default (Peters et al., 2011b). In fact, it cannot be ruled out that a tediously accomplished CCU process is finally environmentally less sustainable than a conventional fossil-based route. Therefore, it is desirable to know whether a specific CCU process is environmentally favorable. For this purpose, a reliable environmental assessment of CCU is required.As indicators for the environmental performance of CCU, a large variety of approaches are proposed ranging from qualitative design principles (Anastas andWarner, 1998) and metrics for 'green' chemistry (Constable et al., 2002) to CCU-specific ad-hoc criteria (Peters et al., 2011b; M¨uller and Arlt, 2014). These approaches are rather intended to guide the development towards 'sustainable' CCU processes than to systematically quantify the actual environmental impacts. In contrast to these approaches, Life-Cycle Assessment (LCA) is a systematic and standardized methodology to analyze the actual environmental impacts of products and processes (ISO 14040, 2009). Although LCA is frequently advocated for the environmental assessment of CCU (Aresta and Dibenedetto, 2007b; Peters et al., 2011b; Quadrelli et al., 2011), it is not.
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Taschenbuch. Zustand: Neu. Druck auf Anfrage Neuware - Printed after ordering - In this volume, Professor He and his coworkers summarize polyethylene glycol (PEG)-promoted CO2 chemistry on the basis of understanding about phase behavior of PEG/CO2 system and reaction mechanism at molecular level. As PEG could be utilized as a green replacement for organic solvents, phase-transfer catalyst, surfactant, support in various reaction systems, significantly promoting catalytic activity and recovering expensive metal catalysts, particularly regarded as a CO2-philic material, the authors focus on special applications of PEG in CO2 capture and utilization, including PEG-functionalized catalysts for efficient transformation of CO2 and PEG-functionalized absorbents for efficient CO2 capture. Furthermore, they describe carbon capture and utilization strategy as an alternative approach to address the energy penalty problem in carbon capture and storage. Interestingly, the authors also discuss PEG radical chemistry in dense CO2 as rather creative and unusual use of PEG,presumably serves as a reaction medium and a radical initiator for radical chemistry.
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In den WarenkorbPaperback. Zustand: New. Ever since humans have existed, they have impacted the earth in many different ways (Redman, 1999). Currently, important impacts are associated with the excessive use of non-renewable fossil fuels such as coal, oil and natural gas. Most fossil fuels are used for electricity generation, heating and mobility (eia, 2011), and as feedstock in the chemical industry (IEA et al., 2013). Moreover, the use of fossil fuels is associated with carbon dioxide emissions (CO2) (IEA, 2014; Leimk¨uhler, 2010). Emitting CO2 into the atmosphere leads to global warming and disrupts the natural carbon cycle (Stocker et al., 2013). To close the disrupted carbon cycle, CO2 can be captured and re-utilized, thereby mitigating global warming and saving fossil resources (Styring et al., 2014).CO2 can be captured from current anthropogenic CO2 sources or directly from the atmosphere. Captured CO2 can then be utilized as valuable physical product "as such"or as alternative carbon feedstock for fuels, chemicals and materials. The general concept of CO2 Capture and Utilization (CCU) can be considered established: already today, CO2 is captured and utilized in processes in the chemical industry (Aresta et al., 2014). However, the scope of CO2 utilization is limited. Despite the existing industrial implementations as well as continuous progress and current efforts in CCU research, most CCU technologies are still in early stages of development. Besides the limited technological readiness, CCU is intrinsically challenging since both capture and utilization of CCU typically require substantial amounts of energy (Sakakura et al., 2007). If the provision of energy relies on fossil resources, indirect CO2 emissions are caused. Therefore, the intuitively expected environmental benefits from using CO2 are not given by default (Peters et al., 2011b). In fact, it cannot be ruled out that a tediously accomplished CCU process is finally environmentally less sustainable than a conventional fossil-based route. Therefore, it is desirable to know whether a specific CCU process is environmentally favorable. For this purpose, a reliable environmental assessment of CCU is required.As indicators for the environmental performance of CCU, a large variety of approaches are proposed ranging from qualitative design principles (Anastas andWarner, 1998) and metrics for 'green' chemistry (Constable et al., 2002) to CCU-specific ad-hoc criteria (Peters et al., 2011b; M¨uller and Arlt, 2014). These approaches are rather intended to guide the development towards 'sustainable' CCU processes than to systematically quantify the actual environmental impacts. In contrast to these approaches, Life-Cycle Assessment (LCA) is a systematic and standardized methodology to analyze the actual environmental impacts of products and processes (ISO 14040, 2009). Although LCA is frequently advocated for the environmental assessment of CCU (Aresta and Dibenedetto, 2007b; Peters et al., 2011b; Quadrelli et al., 2011), it is not.
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Taschenbuch. Zustand: Neu. Capture and Utilization of Carbon Dioxide with Polyethylene Glycol | Zhen-Zhen Yang (u. a.) | Taschenbuch | SpringerBriefs in Molecular Science | xiv | Englisch | 2012 | Springer | EAN 9783642312670 | Verantwortliche Person für die EU: Springer Verlag GmbH, Tiergartenstr. 17, 69121 Heidelberg, juergen[dot]hartmann[at]springer[dot]com | Anbieter: preigu.
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Zustand: Sehr gut. Zustand: Sehr gut | Sprache: Englisch | Produktart: Bücher | In this volume, Professor He and his coworkers summarize polyethylene glycol (PEG)-promoted CO2 chemistry on the basis of understanding about phase behavior of PEG/CO2 system and reaction mechanism at molecular level. As PEG could be utilized as a green replacement for organic solvents, phase-transfer catalyst, surfactant, support in various reaction systems, significantly promoting catalytic activity and recovering expensive metal catalysts, particularly regarded as a CO2-philic material, the authors focus on special applications of PEG in CO2 capture and utilization, including PEG-functionalized catalysts for efficient transformation of CO2 and PEG-functionalized absorbents for efficient CO2 capture. Furthermore, they describe carbon capture and utilization strategy as an alternative approach to address the energy penalty problem in carbon capture and storage. Interestingly, the authors also discuss PEG radical chemistry in dense CO2 as rather creative and unusual use of PEG,presumably serves as a reaction medium and a radical initiator for radical chemistry.
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