VG/Good, tan dj in transparent dw with black titles on spine, contents are clean and unmarked, 406pp. Ex-Royal Aircraft Establishment Library.Weight 600g. A review of the literature published up to late 1978. A specialist periodical report.

Bestandsnummer des Verk�ufers 000194

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Bibliografische Details

Titel

Spectroscopic Properties of Inorganic and Organometallic Compounds Volume 12

Verlag

Chemical Society, London

Erscheinungsjahr

1980

Sprache

Englisch

ISBN-10

0851861032

ISBN-13

9780851861036

Einband

Cloth

Auflage

First Edition

Zustand

Very Good

Zustand des Schutzumschlags

Good

Buchtyp

Ex-Library

Verk�uferkataloge

Chemistry

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Inhaltsangabe

Spectroscopic Properties of Inorganic and Organometallic Compounds provides a unique source of information on an important area of chemistry. Divided into sections mainly according to the particular spectroscopic technique used, coverage in each volume includes: NMR (with reference to stereochemistry, dynamic systems, paramagnetic complexes, solid state NMR and Groups 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of main group and transition element compounds and coordinated ligands; and electron diffraction. Reflecting the growing volume of published work in this field, researchers will find this Specialist Periodical Report an invaluable source of information on current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr

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Spectroscopic Properties of Inorganic and Organometallic Compounds Volume 11

A Review of the Recent Literature Published up to late 1977

By D. M. Adams, E. A. V. Ebsworth

The Royal Society of Chemistry

Chapter 1 Nuclear Magnetic Resonance Spectroscopy By B. E. Mann, 1, 
Chapter 2 Nuclear Quadrupole Resonance Spectroscopy By R. J. Lynch, 152, 
Chapter 3 Microwave Spectroscopy By A. P. Cox, 168, 
Chapter 4 Vibrational Spectra of Small Symmetric Species and of Single Crystals By D. M. Adams and P. N. Gates, 185, 
Chapter 5 Characteristic Vibrational Frequencies of Compounds Containing Main-group Elements By S. Cradock, 218, 
Chapter 6 Vibrational Spectra of Transition-element Compounds By J. S. Ogden, 237, 
Chapter 7 Vibrational Spectra of some Co-ordinated Ligands By G. Davidson, 267, 
Chapter 8 M�ssbauer Spectroscopy By J. D. Donaldson and M. J. Tricker, 329, 
Author Index, 417,

CHAPTER 1

Nuclear Magnetic Resonance Spectroscopy

BY B. E. MANN

1 Introduction

The growth of the use of n.m.r. spectroscopy by inorganic and organometallic chemists and the necessity to restrict the size of this chapter have forced a further reduction in the literature coverage afforded here. Only reviews and books directly relevant to this chapter are included, and the reader who requires a complete list of books and reviews is referred to the Specialist Periodical Reports on n.m.r. spectroscopy where a complete list of reviews and books is given. Reviews which are of direct relevance to a section of this Report are included in the beginning of that section rather than here. Papers where only 1H n.m.r. spectroscopy is used are only included when the 1H n.m.r. spectra make a non-routine contribution but complete coverage of relevant papers is still attempted where nuclei other than the proton are involved. Previously, a partial attempt has been made at cross-referencing between some of the sections, but this is now discontinued.

No books, and only a limited number of reviews, of direct relevance to this chapter have appeared, i.e. 'Fourier Transform Nuclear Magnetic Resonance Spectroscopy through the Periodic Table', 'Semi-empirical Calculations of the Chemical Shifts of Nuclei other than Protons', 'Nuclear Magnetic Resonance of Central Metal Ions in Octahedral Complexes', 'The Structure of Complexes of Mono- and Poly-nucleotides with Metal Ions of the First Transition Group. Part II. Nuclear Magnetic Resonance Studies', 'Structural Features of Hexafluorocomplexes of Noble Metals', 'Application of Halide Ion Magnetic Resonance to Bioinorganic Problems', and 'Conventions and Chemical Shifts in N.M.R.'. This last paper contains a justified attack on the inorganic chemists who quote chemical shifts without stating the sign convention or reference used. This behaviour is common for 11B, 19F, and 31P chemical shifts which are quoted using the 8 scale which implies, according to I.U.P.A.C., that high frequency (low field) is positive. Unfortunately in many cases it is clear that the authors intend the reverse convention and in many more cases it is not clear which sign convention is being used. It is therefore important, especially in papers quoting 11B, 19F, or 31P chemical shifts, for the sign convention to be clearly stated. It is to be hoped that editors and referees will draw the attention of authors to this problem. As far as possible, the sign convention that high frequency is positive has been used throughout this chapter.

A number of papers have been published which are too broadly based to fit into a later section and are included here. 1H N.m.r. spectra of edta and [R(O2CCH2)-NCH2CH2N(CH2CO2)2]3- (R = Me or CH2CH2OH) complexes of diamagnetic ions, including the alkali, alkaline-earth, and rare-earth metals, have been described. Splittings of the methylenic protons of the acetate groups, indicative of long-lived metal-nitrogen bonds, were found for each ligand in the complexes of the cations of higher charge density. The ligand proton chemical shifts were shown to correlate with the effective charge density of the metal ion. Computer analysis of the n.m.r. spectra of complexed pyrrole-A-carbodithiolate to CuII, CdII, PtII, PdII, CoII, and FeIII and of the free ligand indicates little positive charge build-up on the heterocyclic nitrogen atom. Finite-perturbation-theory INDO calculations have been reported for 1JPH, 1JSiH, 2JPCH, and 1JSiCH. These calculations are generally satisfactory. The calculated value of 1JPH in PH3 is too small and the effect of strongly electronegative substituents on the couplings was not completely accounted for. The role of diamagnetic and paramagnetic screening in determining chemical shifts in n.m.r. has been examined for AXn (A is the nucleus) and for AFn-1X (19F). K(A,19F) in [AFn]m- is negative for all compounds where A is a non-transition element (with the exception of compounds with markedly ionic A — F bonding) and most likely positive for compounds where A is a transition element. A correlation was established between the A ns orbital energy and the change in the completely reduced constants C(A,F) for the isoelectronic and isovalent [AFn]m- Pertubation theory was used to find the change in K(A,F) when going from [AF6]m- to [AF5L]m-. A relation was found between the nature of A and the signs and relative values of K(A,19Ftrans) and K(A,19Fcis). The theoretical predictions are in agreement with the experimental results. A comparative analysis was made of the relation between the change in K(A,19F) and the A — F bond strength in the compounds [AF5L]m- and [AF6]m-. 13C N.m.r. spectra can differentiate between S- and N-co-ordinated thiocyanate, and 31P n.m.r. spectroscopy can distinguish between ionic, uni-, and bi-dentate binding of [(RO)2PS2]- to a wide range of elements.

2 Stereochemistry

This section is subdivided into ten parts which contain n.m.r. information about lithium, sodium, potassium, beryllium, magnesium, and transition-metal complexes, presented by Groups, according to the Periodic Table. Within each Group, classification is by ligand type.

Complexes of Group IA and IIA Elements. — 'N.M.R. in Alkali Molecules by Optical Pumping' and 'N.M.R. Spectral Change as a Probe of Chlorophyll Chemistry' have been reviewed.

A survey of the structure and bonding of alkyl-lithium compounds in hydro- carbon solvents has been made. These compounds exist in hydrocarbon solution as either hexamers or tetramers. Increasing chain length results in a lower degree of association. Li+ [CαMePhCH2CMe,]- and K+2[C2MePHCH2CH2C2MePh]2- have 1J(13Cα, 13C) consistent with an sp2-hybridized Cα with relatively little effect on the charge on the coupling constants. Li+[CH2CMe==CHBut]- gave much smaller coupling constants. The 13C n.m.r. spectra of indenyl- and cyclopentadienyl-lithium have been measured. The solvent dependence of the chemical shift was used to probe the π-electron density and hence ion pairing. There was, however, no solvent dependence of the average chemical shifts. 1H and 13C n.m.r. spectra were used to differentiate between (1; M = HgBr) and (2; M = Li, K, ZnBr, MgBr, SiMe3, Mg, or Hg). The nuclear magnetic resonance of Na2 and Cs2 has been measured by the atom-molecular exchange optical pumping method:

σ(Na) - σ(Na2) = (29 [+ or...

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